I firm "No" and put the other cat back in it's usual place.
Thank you voter.
The human's role in a pride of cats is to provide food, shelter, entertainment and affection. Know your place. It's their business deciding who's the boss and your interference won't be welcome. Think I'm full of it? You'll see...
They usually figure out their own "pecking order".
I would let them figure it out .. and don't get involved unless they start fighting.