I really liked Sling Blade's music
The Singles soundtrack. And the soundtrack from the Mission. As different all you can get, but my two favourites.
I don't know if its my favorite, but I probably listened to the Crow soundtrack the most when I was a teenager.
American Graffiti comes to mind first.
indiana jones-john williams
One of my favorites is from "The Last of the Mohicans" it just seems the music perfectly casts not only the mood but the grandeur of the wilderness.