Picard. Because he is the best and has the best voice.
John Archer. Seems the most human, but still true to the feel of a ST captain
James T Kirk,because... yea- verily Mr. Shatner provided dramatic interpretations which were Shakespearean in their complexity whilst maintaining an intergalactic down to earth believability,plus the costumes were more cutting edge.Plus because I am old.And a DOCTOR,Dammmit!
Picard. An intellectual.
Picard... because who doesn't love a French man with an English accent?
Kirk because he represents one third of the personality trilogy with Spock and Bones.
Kirk.. But in the movies, more than the Series